Có dung dịch riêng rẽ các chất sau: CH3COOH, CH2=CHCOOH, CH3CHO, CH3CH2OH. Để phân biệt các dung dịch trên cần dùng ít nhất các thuốc thử nào sau đây?
Có dung dịch riêng rẽ các chất sau: CH3COOH, CH2=CHCOOH, CH3CHO, CH3CH2OH. Để phân biệt các dung dịch trên cần dùng ít nhất các thuốc thử nào sau đây?
A. Quỳ tím, dung dịch AgNO3/NH3 và nước bromine.
B. Quỳ tím và nước bromine.
C. Dung dịch AgNO3/NH3 và nước bromine.
Hãy suy nghĩ và trả lời câu hỏi trước khi xem đáp án
- Bước 1: Dùng quỳ tím.
- $CH_3COOH$ và $CH_2=CHCOOH$ làm quỳ tím hóa đỏ.
- $CH_3CHO$ và $CH_3CH_2OH$ không làm đổi màu quỳ tím.
- Bước 2: Phân biệt $CH_3COOH$ và $CH_2=CHCOOH$, ta dùng nước brom: $CH_2=CHCOOH$ làm mất màu nước brom. $CH_2=CHCOOH + Br_2 \rightarrow CH_2Br-CHBr-COOH$
- Bước 3: Phân biệt $CH_3CHO$ và $CH_3CH_2OH$, ta dùng dung dịch $AgNO_3/NH_3$: $CH_3CHO$ tạo kết tủa Ag. $CH_3CHO + 2AgNO_3 + 3NH_3 + H_2O \rightarrow CH_3COONH_4 + 2Ag + 2NH_4NO_3$
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